Title of article :
Formation of an unusual mixed boric–phosphinic acid ester derived from perfluoropinacol
Author/Authors :
Stelzer، نويسنده , , Othmar and Volkholz، نويسنده , , Matthias and Schmutzler، نويسنده , , Reinhard، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
On treatment of the Me3Si-functional 1,3,2σ5λ5-dioxaphospholane (1) with boron trichloride the novel mixed boric–phosphinic acid ester (3b) of perfluoropinacol is formed in a ring-opening reaction, instead of the expected mixed anhydride (3a) with pentacovalent phosphorus.
Keywords :
Mixed boric–phosphinic acid ester , 1 , 3 , 2?4?5-Dioxaphospholane , Mixed anhydrides , Ring opening
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry