• Title of article

    Reactions of oxalyl fluoride with electrophiles

  • Author/Authors

    Murata، نويسنده , , Junji and Tamura، نويسنده , , Masanori and Sekiya، نويسنده , , Akira، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    97
  • To page
    100
  • Abstract
    The reactions of oxalyl fluoride with electrophiles in the presence of alkali metal fluoride were carried out. In the reaction with CF3CH2OTf (Tf=CF3SO2) or CH3CH2OTf, the synthesis of di-ether (ROCF2CF2OR) and mono-ether (ROCF2COF) was achieved. The difference of the reactivities between these two compounds was discussed from the result of DFT calculations.
  • Keywords
    2-bis(2 , Cesium fluoride , 2-trifluoroethoxy)-1 , 2 , Oxalyl fluoride , 1 , 2-Tetrafluoroethane , 2 , DFT calculation , 1
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2002
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1603423

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1603423