Title of article
2,6-Difluorphenylxenon(II)bis(fluorsulfonyl)amid, -bis(trifluormethylsulfonyl)amid, -tris(fluorsulfonyl)methanid und -bis(trifluormethylsulfonyl)methanid—neue C–Xe–N- und C–Xe–C-Verbindungen?
Author/Authors
Yagupolskii، نويسنده , , Yurii L. and Tyrra، نويسنده , , Wieland and Gnann، نويسنده , , Robert and Maggiarosa، نويسنده , , Nicola and Naumann، نويسنده , , Dieter، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
4
From page
143
To page
146
Abstract
[Xe(2,6-F2C6H3)][N(SO2Rf)2] (Rf=F (1); CF3 (2)) and [Xe(2,6-F2C6H3)][CHn(SO2Rf)3−n] (Rf=F, n=0 (3); CF3, n=1 (4)) are formed on mixing aqueous solutions of [Xe(2,6-F2C6H3)][BF4] and the NH and CH acids, respectively. 1–3 are obtained as colorless solids whereas 4 is unstable and is characterized only by 19F NMR spectroscopy.
menfassung
6-F2C6H3)][N(SO2Rf)2] (Rf=F (1); CF3 (2)) and [Xe(2,6-F2C6H3)][CHn(SO2Rf)3−n] (Rf=F, n=0 (3); CF3, n=1 (4)) are formed on mixing aqueous solutions of [Xe(2,6-F2C6H3)][BF4] and the NH and CH acids, respectively. 1–3 are obtained as colorless solids whereas 4 is unstable and is characterized only by 19F NMR spectroscopy.
Keywords
Fluorophenylxenon , Sulfonylamides , 129Xe NMR spectroscopy , 19F NMR spectroscopy , Sulfonymethanides
Journal title
Journal of Fluorine Chemistry
Serial Year
2002
Journal title
Journal of Fluorine Chemistry
Record number
1603434
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