Title of article
Facile synthesis of 1,1-gem-dialkylperfluoroalkylamines
Author/Authors
Zhang، نويسنده , , Nan and Ayral-Kaloustian، نويسنده , , Semiramis Ayral-Kaloustian، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
3
From page
9
To page
11
Abstract
Tertiary 1,1-gem-dialkylperfluoroalkylamines were prepared by treatment of perfluoroalkylcarboxamides with alkylcerium chlorides, generated from cerium chloride and alkyllithium or alkyl Grignard reagents. The products were easily isolated as the hydrochloride salts. Higher yields were obtained with alkyllithium than with alkyl Grignard reagents.
Keywords
1 , 1-gem-Dialkylperfluoroalkylamines , Perfluoroalkylcarboxamides , Alkylcerium chlorides , bis-Alkylation
Journal title
Journal of Fluorine Chemistry
Serial Year
2002
Journal title
Journal of Fluorine Chemistry
Record number
1603629
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