Title of article
Synthesis of 2-trifluoromethoxyethyl trifluoromethoxyacetate and derived 2-trifluoromethoxyacrylates
Author/Authors
Blazejewski، نويسنده , , Jean-Claude and Anselmi، نويسنده , , Elsa and Wernicke، نويسنده , , Angelika and Wakselman، نويسنده , , Claude، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
6
From page
161
To page
166
Abstract
The synthesis of 2-trifluoromethoxyethyl trifluoromethoxyacetate 2 by oxidation of bis(2-trifluoromethoxyethyl)ether 1 followed by its anionic condensation with aldehydes, ketones and immonium salts under mild conditions, and further dehydration or deamination, enabled the preparation of 3-aryl and 3-alkyl-2-trifluoromethoxacrylates 8a–e as well as the parent 2-trifluoromethoxyacrylate 8f.
Keywords
Ether oxidation , Trifluoromethoxy group , Aldehydes , ketones , Ester condensation , Eschenmoser salt , Acrylates
Journal title
Journal of Fluorine Chemistry
Serial Year
2002
Journal title
Journal of Fluorine Chemistry
Record number
1603652
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