Title of article :
Synthesis in fluorous phase: a convenient synthesis of isolongifolene epoxide and its rearrangement to ketone
Author/Authors :
Ravikumar، نويسنده , , K.S. and Bégué، نويسنده , , Jean-Pierre and Bonnet-Delpon، نويسنده , , Danièle and Ourévitch، نويسنده , , Michèle، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
Aerobic epoxidation of isolongifolene 1 with pivalaldehyde/oxygen in perfluoro-2-butyltetrahydrofuran (FC-75) in the presence of Mn(OAc)3·2H2O as catalyst yielded isolongifolene-epoxide 3 in good yield. The rearrangement of isolongifolene-β-epoxide to ketone 4 was achieved.
Keywords :
Manganese catalyst , Aerobic oxidation , epoxidation , Terpenes , Fluorous phase
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
