• Title of article

    Solvolyis reactions of perfluoro-5-aza-4-nonene, C3F7CFNC4F9

  • Author/Authors

    Siedle، نويسنده , , A.R. and Webb، نويسنده , , Robert J and Newmark، نويسنده , , R.A and Brostrom، نويسنده , , Myles and Weil، نويسنده , , David A and Erickson، نويسنده , , Kristin and Behr، نويسنده , , Fred.E and Young Jr.، نويسنده , , Victor G، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    8
  • From page
    175
  • To page
    182
  • Abstract
    Hydrolysis of the imine perfluoro-5-aza-4-nonene, C3F7CFNC4F9, in ether was studied by several spectroscopic techniques including 17O NMR. The initial product is C3F7CONHC4F9 which is converted to (C3F7CO)2NH and then to C3F7CONH2 and C3F7CO2H. Solvolysis in liquid ammonia afforded the amidine C3F7C(NH)NH2. Reaction with hydrazine produced 3,5-bis(heptafluoropropyl)-1,2,4-triazole whose crystal structure is reported.
  • Keywords
    4-Triazole , Heptafluorobutyramide , 17O NMR , Heptafluorobutyrimide , Perfluoro-5-aza-4-nonene , 3 , 5-bis(Heptafluoropropyl)-1 , Solvolysis , 2
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2003
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1607640

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1607640