Title of article
Synthesis and characterisation of bis(pentafluorophenyl)antimony(V) cations, [(C6F5)2SbL3]3+
Author/Authors
Singhal، نويسنده , , Kiran and Kant، نويسنده , , Ravi and Raj، نويسنده , , Prem and Goswami، نويسنده , , A.K.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
229
To page
232
Abstract
Pentacoordinate complex cations of the general formula [(C6F5)2SbL3]3+ stabilized as solid salts in combination with tetraphenylborate (BPh4), tetrafluorobroate (BF4) anions, where L=DMSO, Ph3AsO, PyO, DMF, α-, β- and γ-picoline have been isolated. The newly formed complexes were characterized by elemental analysis, molar conductance measurements, solid-state IR and 1H and 19F NMR. From these results, a five-fold coordination around antimony was required.
Keywords
Trigonal bipyramidal , 1H and 19F NMR , IR , 1:3 Electrolytes , Bis(pentafluorophenyl)antimony(V) cations
Journal title
Journal of Fluorine Chemistry
Serial Year
2003
Journal title
Journal of Fluorine Chemistry
Record number
1607664
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