Title of article
Thia-Fries rearrangement of aryl triflinates to trifluoromethanesulfinylphenols
Author/Authors
Chen، نويسنده , , Ximin and Tordeux، نويسنده , , Marc and Desmurs، نويسنده , , Jean-Roger and Wakselman، نويسنده , , Claude، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
6
From page
51
To page
56
Abstract
Aryl triflinates are transformed to trifluoromethanesulfinylphenols in the presence of aluminum trichloride in dichloromethane at room temperature according to a thia-Fries rearrangement process. Rigorous exclusion of oxygen is necessary in order to avoid the formation of 2,2′-dihydroxybiaryls as secondary products.
Keywords
Dihydroxybiaryls , Sulfinates , sulfoxides , Rearrangement
Journal title
Journal of Fluorine Chemistry
Serial Year
2003
Journal title
Journal of Fluorine Chemistry
Record number
1607699
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