Title of article
Selective mono- and di{(perfluoroalkyl)acylation} of ferrocene
Author/Authors
Hazafy، نويسنده , , David and Sobocikov?، نويسنده , , Marie and ?t?pni?ka، نويسنده , , Petr and Ludv??k، نويسنده , , Ji??? and Kotora، نويسنده , , Martin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
5
From page
177
To page
181
Abstract
The selective synthesis of mono- and 1,1′-di{(perfluoroalkyl)acylated} ferrocenes by Friedel–Crafts acylation with (perfluoroalkyl)acyl halides is described. The acyl derivatives were further converted to the corresponding (perfluoroalkyl)alkyl ferrocenes by reduction of the carbonyl group with LiAlH4/AlCl3. Electrochemical studies of all the obtained substituted ferrocenes were carried out to assess the influence of the perfluoroalkyl ponytails on their redox behavior.
Keywords
Perfluoroalkylated ferrocenes , Ferrocene , Perfluoroalkylation , Perfluoroacylation
Journal title
Journal of Fluorine Chemistry
Serial Year
2003
Journal title
Journal of Fluorine Chemistry
Record number
1607895
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