Title of article
One step synthesis of 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals in an ionic liquid
Author/Authors
Kitazume، نويسنده , , Tomoya and Nagura، نويسنده , , Hirokatsu and Koguchi، نويسنده , , Shinichi، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
79
To page
82
Abstract
Investigation of one step synthesis of 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals has been carried out using versatile aldehydes, tri- or di-fluoroacetaldehyde ethyl hemiacetal in the presence of diethylaminotrimethylsilane (DEATMS) in an ionic liquid, and it was demonstrated that this route enabled us to successfully construct 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals with the high level selectivity of geometric isomers.
Keywords
2-Substituted 3-tri-(or di-)fluoromethyl-2-propenals , stereoselectivity , One step synthesis
Journal title
Journal of Fluorine Chemistry
Serial Year
2004
Journal title
Journal of Fluorine Chemistry
Record number
1607947
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