Title of article
An efficient enantioselective total synthesis of a trifluoromethyl analog of blastmycinolactol
Author/Authors
Ramachandran، نويسنده , , P.Veeraraghavan and Padiya، نويسنده , , Kamlesh J and Reddy، نويسنده , , M.Venkat Ram and Brown، نويسنده , , Herbert C، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
5
From page
579
To page
583
Abstract
A novel synthetic strategy for the total synthesis of fluorinated analog of blastmycinolactol has been developed using α-pinene based alkoxyallylboration, chelation controlled diastereoselective reduction, and a single step lactonization of the 1,4-diol to the γ-lactone as key steps.
Keywords
Chelation controlled diastereoselective reduction , ?-pinene , Alkoxyallylboration , Hydroboration , Anti-alkylation , Ley’s oxidation , Dicyclohexylborane
Journal title
Journal of Fluorine Chemistry
Serial Year
2004
Journal title
Journal of Fluorine Chemistry
Record number
1608140
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