• Title of article

    Photochemistry of fluorophenyl azides in aniline: Asymmetric fluoroazobenzenes by NH singlet nitrene insertion

  • Author/Authors

    Leyva، نويسنده , , Elisa and Sagredo، نويسنده , , Ruben and Moctezuma، نويسنده , , Edgar، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    7
  • From page
    741
  • To page
    747
  • Abstract
    Several fluorophenyl azides were photolyzed with aniline at room temperature. Only pentafluoro and 2,6-difluorophenyl azides gave asymmetrical fluoroazobenzenes as the major products. These products were generated by singlet NH insertion reaction with aniline followed by oxidation of the resulting aromatic hydrazine.
  • Keywords
    photochemistry , Fluoroazobenzenes , Fluorophenylazides , Singlet phenylnitrene
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2004
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1608207