Title of article
Perfluoroorganosilver(I) compounds
Author/Authors
Tyrra، نويسنده , , Wieland and Naumann، نويسنده , , Dieter، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
8
From page
823
To page
830
Abstract
A survey of different methods to prepare perfluoroorganosilver(I) compounds is given. The reaction of silver(I) fluoride with trimethyl(perfluoroorgano)silanes offers a new convenient method for the syntheses of these compounds. The formation of bis(perfluoroorgano)argentates(I) is discussed and the crystal structure of [PNP][Ag(CF3)Cl] is described. Many examples of the application of perfluoroorganosilver(I) compounds as excellent synthons in nucleophilic substitutions and oxidative perfluoroorganylations are given.
Keywords
silver , Perfluoroorgano , Oxidation , Synthesis
Journal title
Journal of Fluorine Chemistry
Serial Year
2004
Journal title
Journal of Fluorine Chemistry
Record number
1608230
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