Title of article
Reduction of 4-fluoro-5-(1,1,2,2-tetrafluoroethyl)-3H-1,2-dithiole-3-thione with sodium sulfide: Synthesis of fluoro-containing sulfur-rich heterocycles
Author/Authors
Fesun، نويسنده , , Igor M. and Rozhenko، نويسنده , , Alexander B. and Timoshenko، نويسنده , , Vadim M.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
6
From page
774
To page
779
Abstract
Treatment of 4-fluoro-5-(1,1,2,2-tetrafluoroethyl)-3H-1,2-dithiole-3-thione with 2 equivalents of sodium sulfide gives after acidification 3,4-difluoro-2-mercapto-1,6,6aλ4-trithiapentalene, which can be further reduced by sodium sulfide to 3,5-difluoro-4-mercapto-thiopyran-2-thione.
Keywords
Thiopyranthione , 2-Dithiole-3-thione , 1 , Calculations , Thiocarbonyl compounds , Trithiapentalene , DFT , MP2 , Reduction
Journal title
Journal of Fluorine Chemistry
Serial Year
2006
Journal title
Journal of Fluorine Chemistry
Record number
1609261
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