Title of article
Fluoropropenoates as dienophiles in the Diels–Alder reaction
Author/Authors
Patrick ، نويسنده , , Timothy B. and Fianu، نويسنده , , Cynthia and Pak، نويسنده , , Eric and Zaksas، نويسنده , , Kasey and Neal، نويسنده , , Bradley E.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
861
To page
864
Abstract
Several fluorinated alkenes were prepared from known ethyl (R)-2-fluoro-4,5-dihydroxyisopropylidine-2-pentenoate (1). The fluoroalkenoates were tested as dienophiles with several dienes and showed cycloaddition only with the very reactive diene, 1,3-diphenylisobenzofuran (5). Fluorobutenolide 2 reacted with 5 to produce the endo-syn adduct 9 in a highly stereoselective manner.
Keywords
Fluoroalkene , cycloaddition , Diels–Alder
Journal title
Journal of Fluorine Chemistry
Serial Year
2006
Journal title
Journal of Fluorine Chemistry
Record number
1609293
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