Title of article
A convenient and efficient method for incorporation of pentafluorosulfanyl (SF5) substituents into aliphatic compounds
Author/Authors
Dolbier Jr.، نويسنده , , William R. and Aït-Mohand، نويسنده , , Samia and Schertz، نويسنده , , Tyler D. and Sergeeva، نويسنده , , Tatiana A. and Cradlebaugh، نويسنده , , Joseph A. and Mitani، نويسنده , , Akira and Gard، نويسنده , , Gary L. and Winter، نويسنده , , Rolf W. and Thrasher، نويسنده , , Joseph S.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
9
From page
1302
To page
1310
Abstract
Both SF5Cl and SF5Br undergo smooth, high yield addition to alkenes and alkynes under the mild free radical chain reaction conditions of triethylborane initiation at low temperature, although the SF5Br chemistry is somewhat limited by its competing high electrophilic reactivity with electron rich alkenes. The SF5Cl addition reaction is relatively insensitive to a wide variety of non-allylic functionalities.
Keywords
Pentafluorosulfanyl substituent , Free radical chain reaction , SF5Cl , Triethylborane initiation , SF5Br
Journal title
Journal of Fluorine Chemistry
Serial Year
2006
Journal title
Journal of Fluorine Chemistry
Record number
1609420
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