Title of article :
Rearrangement and fluorination of quinidinone in superacid
Author/Authors :
Vincent Chagnault، نويسنده , , Vincent and Thibaudeau، نويسنده , , Sébastien and Jouannetaud، نويسنده , , Marie-Paule and Jacquesy، نويسنده , , Jean-Claude and Cousson، نويسنده , , Alain and Bachmann، نويسنده , , Christian، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
In HF/SbF5 at −78 °C, quinidinone 1 yields fluoroketone 3 (50% yield). The reaction implies a cyclic carboxonium ion as an intermediate, which reacts through a concerted rearrangement and fluorination to yield ketone 3.
Keywords :
Superacids , Rearrangement , Cinchona alkaloids , Carboxonium ion , fluorination
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
