Title of article :
Synthesis of 1,1-difluoroethylsilanes and their application for the introduction of the 1,1-difluoroethyl group
Author/Authors :
Mogi، نويسنده , , Ryo and Morisaki، نويسنده , , Kazuo and Hu، نويسنده , , Jinbo and Prakash، نويسنده , , G.K. Surya and Olah، نويسنده , , George A.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
1,1-Difluoroethysilanes (R3SiCF2CH3, R = Me or Et) were synthesized from 1,1-difluoroethyl phenyl sulfone and chlorosilanes using magnesium metal via reductive 1,1-difluoroethylation. It was confirmed that 1,1-difluoroethylsilanes were effective 1,1-difluoroethylating reagents for carbonyl compounds.
Keywords :
1-Difluoroethylation , 1 , 1-Difluoroethylsilane , 1-Difluoroethyl phenyl sulfone , Magnesium , 1 , 1
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
