Title of article :
Structure of C, N-chelated nButyltin(IV) fluorides and their use as fluorinating agents of some chlorosilanes, chlorophosphine and metal halides
Author/Authors :
?vec، نويسنده , , Petr and Nov?k، نويسنده , , Petr and N?dvorn?k، نويسنده , , Milan and Pad?lkov?، نويسنده , , Zde?ka and C?sa?ov?، نويسنده , , Ivana and Kol??ov?، نويسنده , , Lenka and R??i?ka، نويسنده , , Ale? and Hole?ek، نويسنده , , Jaroslav، نويسنده ,
Abstract :
The tin atom in the solid-state structure of {2-[(CH3)2NCH2]C6H4}nBu2SnF is five coordinated with carbon atoms in equatorial and fluorine and nitrogen atoms in axial positions. The fluorination of {2-[(CH3)2NCH2]C6H4}nBuSnCl2 is described by NMR methods. The successful attempts to fluorinate various chlorosilanes, chlorophosphine and metal halides are also reported.
Keywords :
C , structure , N-ligand , Organotin(IV) fluorides
