Author/Authors :
Sato، نويسنده , , Kazuyuki and Higashinagata، نويسنده , , Makoto and Yuki، نويسنده , , Takashi and Tarui، نويسنده , , Atsushi and Omote، نويسنده , , Masaaki and Kumadaki، نويسنده , , Itsumaro and Ando، نويسنده , , Akira، نويسنده ,
Abstract :
The treatment of silyl enol ethers with fluoroalkyl halides (Rf–X) in the presence of RhCl(PPh3)3 gave α-fluoroalkylated ketones. It seems that a rhodium complex derived from the silyl enol ether and RhCl(PPh3)3 played an important role for the oxidative addition of fluoroalkyl halides and the reductive elimination of the product.
Keywords :
fluorine , Rhodium , Silyl enol ethers , ?-Fluoroalkylation
