Title of article :
Synthesis of fluoroalkyl-δ-lactones from polyfluoroalkyl iodides and 5-hexenoic acids
Author/Authors :
Fang، نويسنده , , Xiang and Ying، نويسنده , , Qi and Chen، نويسنده , , Yang and Yang، نويسنده , , Xueyan and Yang، نويسنده , , Xianjin and Wu، نويسنده , , Fanhong، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
The polyfluoroalkyl-lactonization of 5-hexenoic acids with the polyfluoroalkyl iodides initiated by sodium dithionite was carried out in aqueous acetonitrile, providing an efficient method for the synthesis of fluorine-containing δ-valerolactones. Formation of RfCH2CHCH(CH2)2COOH appeared to be unexpected minor product in sulfinatodehalogenation reagents.
Keywords :
5-Hexenoic acids , ?-Valerolactone , Polyfluoroalkyl iodide , Polyfluoroalkyl-lactonization , Sodium dithionite
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
