Title of article
Yb[N(SO2C8F17)2]3-catalyzed allylation of 1,3-dicarbonyl compounds with allylic alcohols in a fluorous biphase system
Author/Authors
Shen، نويسنده , , Ming-Gui and Cai، نويسنده , , Chun-Li Yi، نويسنده , , Wen-Bin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
5
From page
595
To page
599
Abstract
Allylation of 1,3-dicarbonyl compounds with allylic alcohols was successfully accomplished using rare earth metal (III) bis(perfluorooctanesulfonyl)imide [RE(NPf2)3, RE = La∼Lu] as catalysts in fluorous solvents. Ytterbium bis(perfluorooctanesulfonyl)imide [Yb(NPf2)3] catalyzes the high efficient reaction of allylation in fluorous solvents. By simple separation, fluorous phase containing only catalyst can be reused several times.
Keywords
allylation , Fluorous biphasic catalysis , Allylic alcohols , Rare earth(III) bis(perfluorooctanesulfonyl)amide
Journal title
Journal of Fluorine Chemistry
Serial Year
2009
Journal title
Journal of Fluorine Chemistry
Record number
1610534
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