Title of article :
Reaction of the Ruppert–Prakash reagent with perfluorosulfonic acids
Author/Authors :
Levin، نويسنده , , Vitalij V. and Dilman، نويسنده , , Alexander D. and Belyakov، نويسنده , , Pavel A. and Struchkova، نويسنده , , Marina I. and Tartakovsky، نويسنده , , Vladimir A.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Abstract :
A new property of Me3SiCF3 to undergo C–F bond activation upon interaction with perfluorosulfonic acids is described. The reaction is catalyzed by titanium tetrachloride and affords difluoromethyl perfluorosulfonates in good yields.
Keywords :
Trifluoromethyltrimethylsilane , Perfluorosulfonic acids , C–F bond activation
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
