Title of article
Stereoselective fluorination of methylenecyclopropanes with N-F reagents: A modular entry to γ-fluorohomoallylic sulfonimides and γ-fluorohomoallylic amides
Author/Authors
Fu، نويسنده , , Weijun and Zou، نويسنده , , Guanglong and Zhu، نويسنده , , Ya-Mei and Hong، نويسنده , , Dongfeng and Deng، نويسنده , , Dongsheng and Xun، نويسنده , , Chen-xi JI، نويسنده , , Baoming، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
5
From page
996
To page
1000
Abstract
A convenient and efficient method for fluorination of methylenecyclopropanes is reported. This is exemplified in the stereoselective preparation of N-[(E)-3-fluorobut-3-en-1-yl]-benzenesulfonimides by the reaction of methylenecyclopropanes with N-fluorobenzenesulfonimide in good to excellent yields. Moreover, γ-fluorohomoallylic amides are synthesized using Selectfluor in R3CN at 60 °C.
Keywords
methylenecyclopropanes , fluorination , N-Fluorobenzenesulfonimide , Selectfluor , stereoselective
Journal title
Journal of Fluorine Chemistry
Serial Year
2009
Journal title
Journal of Fluorine Chemistry
Record number
1610668
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