Title of article
The reactions of 3,7-dimethylenebicyclo[3.3.1]nonane, norbornadiene and cis,cis-1,5-cyclooctadiene with pentafluoro-λ6-sulfanyl chloride
Author/Authors
Ponomarenko، نويسنده , , Maxim V. and Serguchev، نويسنده , , Yurii A. and Rِschenthaler، نويسنده , , Gerd-Volker، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
4
From page
270
To page
273
Abstract
Radical transannular cyclizations of the non-conjugated dienes, such as 3,7-dimethylenebicyclo[3.3.1]nonane and norbornadiene with SF5Cl upon UV-irradiation led to the corresponding SF5-substituted 3,7-noradamantane and nortricyclanes with high yields. Radical reaction of cis,cis-1,5-cyclooctadiene with SF5Cl led to a product of SF5Cl addition to one of the diene double bonds either UV-irradiation or triethylborane were used for radical initiation.
Keywords
Transannular cyclizations , 3 , Norbornadiene , CIS , cis-1 , 5-Cyclooctadiene , Pentafluorosulfanyl substituent , SF5Cl
Journal title
Journal of Fluorine Chemistry
Serial Year
2010
Journal title
Journal of Fluorine Chemistry
Record number
1610814
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