Title of article
Replacement of BF4− by PF6− makes Selectfluor greener
Author/Authors
Jin، نويسنده , , Zhuang and Xu، نويسنده , , Bo and DiMagno، نويسنده , , Stephen G. and Hammond، نويسنده , , Gerald B.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
5
From page
226
To page
230
Abstract
A combination of F-TEDA-PF6 and CuBr (0.1 equiv.) provides a potent oxidant that readily oxidizes amides to provide imides at room temperature. Replacement of BF4−, the anion of Selectfluor (F-TEDA-BF4), by PF6−, dramatically reduces CuBr loading in this oxidative reaction. A possible rationale for this dramatic counterion effect is provided.
Keywords
Imides , Selectfluor , Amide oxidation
Journal title
Journal of Fluorine Chemistry
Serial Year
2012
Journal title
Journal of Fluorine Chemistry
Record number
1611892
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