Title of article :
Formation and structure of a fluorinated [2.2]paracyclophan-1-ene
Author/Authors :
Amii، نويسنده , , Hideki and Hayashi، نويسنده , , Ryotaro and Seo، نويسنده , , Motoharu and Katahira، نويسنده , , Yukako and Kobayashi، نويسنده , , Akira and Uneyama، نويسنده , , Kenji، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
The transformation of the bridging linkage in 1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane (AF4) has been investigated. Mg-promoted defluorinative silylation of AF4 gave 2,9,9,10,10-pentafluoro-1-trimethylsilyl[2.2]paracyclophan-1-ene, whose structure was confirmed by X-ray crystallography.
Keywords :
Paracyclophane , Cyclophan-1-ene , defluorination , Magnesium , Silicon
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
