Title of article
Novel electrochemical pathway to fluoroalkyl phosphines and phosphine oxides
Author/Authors
Mikhaylov، نويسنده , , Dmitry Y. and Gryaznova، نويسنده , , Tatyana V. and Dudkina، نويسنده , , Yulia B. and Polyancev، نويسنده , , Fedor M. and Latypov، نويسنده , , Shamil K. and Sinyashin، نويسنده , , Oleg G. and Budnikova، نويسنده , , Yulia H. Budnikova، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
178
To page
182
Abstract
Novel versatile electrocatalytic route for obtaining fluoroalkylated phosphines and phosphine oxides from white phosphorous or diphenylchlorophosphine is discussed. This process occurs under electrochemical generation of nickel complexes in low oxidation state during undivided electrolysis of organofluorine iodides and phosphorous-containing substrate in mild conditions without supporting electrolyte.
Keywords
Electrocatalysis , White phosphorus , Nickel complex , Fluoroalkyl halides , Fluorinated phosphines
Journal title
Journal of Fluorine Chemistry
Serial Year
2013
Journal title
Journal of Fluorine Chemistry
Record number
1612085
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