Title of article :
Nucleophilic trifluoromethylation of anhydrides employing (trifluoromethyl)trimethylsilane: Synthesis of γ-trifluoromethylated γ-butyrolactones
Author/Authors :
Masusai، نويسنده , , Chonticha and Soorukram، نويسنده , , Darunee and Kuhakarn، نويسنده , , Chutima and Tuchinda، نويسنده , , Patoomratana and Reutrakul، نويسنده , , Vichai and Pohmakotr، نويسنده , , Manat، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Pages :
6
From page :
37
To page :
42
Abstract :
Fluoride-catalyzed nucleophilic trifluoromethylation of acid anhydrides using CF3SiMe3 provided the corresponding γ-hydroxy-γ-trifluoromethyl-γ-butyrolactones. The utility of these adducts was further demonstrated by treatment with Grignard reagents, leading to γ-trifluoromethylated γ-butyrolactones.
Keywords :
?-butyrolactones , Ruppert–Prakash reagent , Anhydrides , trifluoromethylation
Journal title :
Journal of Fluorine Chemistry
Serial Year :
2013
Journal title :
Journal of Fluorine Chemistry
Record number :
1612092
Link To Document :
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