Experimental and theoretical studies on the thermal decomposition of 1,1,2,2,3,3,4-heptafluorocyclopentane

1,1,2,2,3,3,4-Heptafluorocyclopentane (F7A) is regarded as the ideal replacement of HCFC, PFC and HFC due to its good environmental performance and low-toxicity. For the application in fire protection area, the fire extinguishing concentration of F7A is 8.4% (volume) that measured by the cup burner. The ecological toxicology is negligible by measuring the acute inhalation toxicity and acute oral toxicity. The ozone depletion potential is zero and the global warming potential is below 150, so F7A is believed to be a kind of potential halon replacements. However, its interaction with flames has never been reported, which causes great inconvenience for investigating its fire suppression mechanism. In this paper, a tubular pyrolysis reactor is utilized to explore the decomposition process of F7A at the temperature ranging from 20 °C to 800 °C and the pyrolysis products are analyzed by GC and GC–MS. Further, the activation energy is calculated using the first order reaction kinetics model and the possible dissociation pathways and decomposition products are deduced using the ab inito and density functional theory. By coupling experimental results and theoretical calculation, characteristics involved in the decomposition of F7A are investigated. It is expected that these investigation results would be of great help to the further study of the fire suppression mechanism of F7A.