Title of article :
Synthesis and electrospinning carboxymethyl cellulose lithium (CMC-Li) modified 9,10-anthraquinone (AQ) high-rate lithium-ion battery
Author/Authors :
Qiu، نويسنده , , Lei and Shao، نويسنده , , Ziqiang and Liu، نويسنده , , Minglong and Wang، نويسنده , , Jianquan and Li، نويسنده , , Pengfa and Zhao، نويسنده , , Ming، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Pages :
7
From page :
986
To page :
992
Abstract :
New cellulose derivative CMC-Li was synthesized, and nanometer CMC-Li fiber was applied to lithium-ion battery and coated with AQ by electrospinning. Under the protection of inert gas, modified AQ/carbon nanofibers (CNF)/Li nanometer composite material was obtained by carbonization in 280 °C as lithium battery anode materials for the first time. The morphologies and structures performance of materials were characterized by using IR, 1H NMR, SEM, CV and EIS, respectively. Specific capacity was increased from 197 to 226.4 mAh g−1 after modification for the first discharge at the rate of 2C. Irreversible reduction reaction peaks of modified material appeared between 1.5 and 1.7 V and the lowest oxidation reduction peak of the difference were 0.42 V, the polarization was weaker. Performance of cell with CMC-Li with the high degree of substitution (DS) was superior to that with low DS. Cellulose materials were applied to lithium battery to improve battery performance by electrospinning.
Keywords :
electrospinning , Cellulose Derivatives , Lithium-ion battery , Anode materials AQ , CMC-Li
Journal title :
CARBOHYDRATE POLYMERS
Serial Year :
2014
Journal title :
CARBOHYDRATE POLYMERS
Record number :
1625689
Link To Document :
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