Title of article
Infrared photoreaction of 2-chloroethyltrifluorosilane
Author/Authors
Dementyev، نويسنده , , Petr S. and Nizovtsev، نويسنده , , Anton S. and Chesnokov، نويسنده , , Evgenii N. Shepelenko، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
77
To page
80
Abstract
Infrared laser dissociation of 2-chloroethyltrifluorosilane has been studied in light of silicon isotopes separation. The reaction occurs via beta-elimination mechanism to yield ethylene and chlorotrifluorosilane as products. The dissociation has a relatively low energy barrier what was confirmed by high-level quantum chemical calculations. High enrichment of 30Si isotope was demonstrated.
Keywords
Silicon isotopes separation , Infrared photodissociation , 2-chloroethyltrifluorosilane
Journal title
Journal of Photochemistry and Photobiology:A:Chemistry
Serial Year
2011
Journal title
Journal of Photochemistry and Photobiology:A:Chemistry
Record number
1626234
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