Title of article
Magnesium mediated carbometallation of propargyl alcohols: direct routes to dihydroxydienes and enediyne alcohols
Author/Authors
Forgione، نويسنده , , Pat and Fallis، نويسنده , , Alex G، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
11
To page
15
Abstract
The addition of vinyl and alkynyl Grignard reagents to propargyl alcohols for the direct synthesis of dihydroxydienes and enediyne alcohols from a one pot reaction is described. These products arise from the putative magnesium chelate intermediate 2 upon reaction with the appropriate electrophile.
Keywords
Diene , propargyl , Diol , Enediyne , Magnesium
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1635922
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