Title of article
Ion-molecular reactions of free phenylium ions, generated by tritium β-decay with bidentate arenes
Author/Authors
Shchepina، نويسنده , , N.E and Nefedov، نويسنده , , V.D and Toropova، نويسنده , , M.A and Avrorin، نويسنده , , V.V and Lewis، نويسنده , , Scott B and Mattson، نويسنده , , Bruce، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
3
From page
25
To page
27
Abstract
Generation of free phenylium ions, obtained by tritium β-decay and their ion-molecular reactions with bidentate arenes are described. The elaborated nuclear-chemical method has been used for the synthesis of tritium labeled organic derivatives using halobenzenes. Two alternative pathways for interaction of the phenylium ion with the bidentate arene, addition to the lone pair of the halogen or substitution on the aromatic ring, were revealed.
Keywords
Labeling , Radiation chemistry , halogen compounds , Halogens
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1635928
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