Title of article
Copper(I)-catalyzed cross-coupling reaction of acylzirconocene complexes with allylic and/or propargylic halides
Author/Authors
Hanzawa، نويسنده , , Yuji and Narita، نويسنده , , Kensuke and Taguchi *، نويسنده , , Takeo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
109
To page
112
Abstract
Efficient cross-coupling reaction of acylzirconocene chloride with allylic and/or propargylic halides was attained by utilizing a catalytic amount of a Cu(I) salt to give allylic and/or allenic ketones, respectively, in good yields. The mild Cu(I)-catalyzed reaction of acylzirconocene chloride offered an alternative protocol for the generation of an ‘unmasked’ acyl anion.
Keywords
zirconium , coupling reactions , Zirconium compounds , copper catalyst
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1635963
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