Author/Authors :
Yanase، نويسنده , , Manabu and Matsuoka، نويسنده , , Miho and Tatsumi، نويسنده , , Yuki and Suzuki، نويسنده , , Masataka and Iwamoto، نويسنده , , Hajime and Haino، نويسنده , , Takeharu and Fukazawa، نويسنده , , Yoshimasa، نويسنده ,
Abstract :
Thermodynamic parameters for the supramolecular complex formation of fullerene C60 with calix[5]arene receptors are reported. The entropy change in chloroform is negative, but in toluene is positive, suggesting the tight solvation around the guest in toluene. Desolvation of the guest plays an important role in the supramolecular complex formation in toluene.
