Title of article
An efficient and stereoselective construction of the C(9)–C(17) dihydropyran segment of swinholides A–C via a novel reductive cleavage of an epoxy aldehyde
Author/Authors
Hayakawa، نويسنده , , Hiroyuki and Miyashita، نويسنده , , Masaaki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
707
To page
711
Abstract
An efficient and highly stereoselective construction of the C(9)–C(17) dihydropyran segment of swinholides A–C, which involves a novel reductive cleavage of an epoxy aldehyde by an organoselenium reagent and the intramolecular conjugate addition of an acetal alkoxide anion of δ-hydroxy-α,β-unsaturated ester as the key steps, is described.
Keywords
Reduction , epoxides , Aldehydes , swinholides , Pyrans , stereocontrol
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636216
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