Asymmetric Strecker reactions of ketimines catalysed by titanium-based complexes
Author/Authors :
Byrne، نويسنده , , Janice J and Chavarot، نويسنده , , Murielle and Chavant، نويسنده , , Pierre-Yves and Vallée، نويسنده , , Yannick، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Pages :
4
From page :
873
To page :
876
Abstract :
The asymmetric addition of TMSCN to a ketimine has been achieved by use of catalytic quantities of chiral titanium(IV) complexes. Fast conversions together with enantiomeric excesses as high as 59% have been achieved.