Title of article :
Aromatic ring hydroxylation of flavanones by dimethyldioxirane
Author/Authors :
Bernini، نويسنده , , Roberta and Mincione، نويسنده , , Enrico and Sanetti، نويسنده , , Anna and Mezzetti، نويسنده , , Maurizio and Bovicelli *، نويسنده , , Paolo، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Pages :
4
From page :
1087
To page :
1090
Abstract :
The selective and efficient oxidation of flavanones with dimethyldioxirane (DMD) is reported. Aromatic rings carrying methoxy groups were selectively hydroxylated in neutral and acidic media. In the latter case inversion of chemoselectivity with respect to the benzylethereal position was observed. This behaviour was exploited to obtain polyhydroxylated flavanones, which are compounds with potential antioxidant and biological properties.
Keywords :
hydroxylation , Dioxirane , Flavanones
Journal title :
Tetrahedron Letters
Serial Year :
2000
Journal title :
Tetrahedron Letters
Record number :
1636423
Link To Document :
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