Title of article
Synthesis of 1-p-tolylsulfinyl-1,3-dienes by intramolecular Heck reactions
Author/Authors
Mar Segorbe، نويسنده , , M and Adrio، نويسنده , , Javier and Carretero، نويسنده , , Juan C، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
1983
To page
1986
Abstract
The first examples of the synthesis of 1,3-dienyl sulfoxides by Heck reactions are described. Both racemic and enantiomerically pure exocyclic 1-p-tolylsulfinyl-1,3-dienes 1 are readily prepared by the intramolecular Heck reaction of their corresponding vinyl iodides in the presence of Pd(OAc)2 as catalyst and Ag2CO3 as base.
Keywords
cyclization , Heck reaction , sulfoxides , 3-dienes , 1 , PALLADIUM
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636621
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