Title of article
Acid-promoted rearrangement of 2-aryl-2,3-epoxy acylates: construction of chiral benzylic quaternary carbon centers
Author/Authors
Kita، نويسنده , , Yasuyuki and Furukawa، نويسنده , , Akihiro and Futamura، نويسنده , , Junko and Higuchi، نويسنده , , Kazuhiro and Ueda، نويسنده , , Koichiro and Fujioka، نويسنده , , Hiromichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
2133
To page
2136
Abstract
The reactions of 2-aryl-2,3-epoxy acylates with BF3·Et2O were examined in detail. Trans-2-aryl-2,3-epoxy acylates afforded the rearranged products in good yields via the C2-carbocation intermediates. The reaction was used for constructing the optically active benzylic quaternary carbon center.
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636655
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