Author/Authors :
Nakamura، نويسنده , , Yosuke and Asami، نويسنده , , Aya and Inokuma، نويسنده , , Seiichi and Ogawa، نويسنده , , Toshio and Kikuyama، نويسنده , , Munehiro and Nishimura، نويسنده , , Jun، نويسنده ,
Abstract :
The reaction of [60]fullerene with bis-o-quinodimethane precursor 3 containing a dibenzo-18-crown-6 moiety provided preferentially trans-4 bisadduct 5a along with a small amount of cis-2 bisadduct 5b. These bisadducts showed different ionophoric properties from each other; 5a exhibited a high complexing ability toward K+ ion, while 5b hardly showed complexation with any alkali metal ions.
Keywords :
Diels–Alder reaction , Crown Ethers , Fullerenes , complexation , Regioselective synthesis
