Title of article
Dichlorotin oxide-catalyzed new direct functionalization of olefins: synthesis of trans β-azidohydrins and 1,2-diols
Author/Authors
Sakurada، نويسنده , , Isao and Yamasaki، نويسنده , , Shingo and Kanai، نويسنده , , Motomu and Shibasaki، نويسنده , , Masakatsu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
2415
To page
2418
Abstract
We have succeeded in developing direct syntheses of trans β-azidohydrins and trans 1,2-diol derivatives from olefins catalyzed by dichlorotin oxide. The regioselectivity of these reactions with tri-substituted olefins is high (10:1 in the synthesis of 1,2-diol derivatives) to excellent (>99:1 in the synthesis of azidohydrins). It has been found that these reactions do not proceed via epoxides.
Keywords
dichlorotin oxide , trans ?-substituted alcohol , Olefin
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636783
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