Title of article :
Is the halogen–metal exchange faster than deprotonation in the reaction of ortho-carboranyl aryl bromide with butyllithium?
Author/Authors :
Lamrani، نويسنده , , Mouad and Hamasaki، نويسنده , , Ryo and Yamamoto، نويسنده , , Yoshinori، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
The Br–Li exchange of bromophenyl-ortho-carborane 1 is faster than the deprotonation of the acidic C–H hydrogen of the carborane cage. The resulting phenyl anion undergoes rapid proton exchange to give the cluster anion.
Keywords :
Metal–halogen exchange , Carborane , Electrochemistry , proton transfer
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters