Title of article :
Synthesis, structure, and catalytic function of a disulfide-bridged dicopper(I) complex
Author/Authors :
Ohta، نويسنده , , Takehiro and Tachiyama، نويسنده , , Takashi and Yoshizawa، نويسنده , , Kazunari and Yamabe، نويسنده , , Tokio، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
A disulfide-bridged dicopper(I) complex [Cu2(Py2SSPy2)](ClO4)2 (1), synthesized by the redox reaction of a Cu(II) salt with a thiol-containing N3S-donor ligand, N,N-bis[2-(2-pyridyl)ethyl]-2-mercapto-2-methylpropylamine (Py2SH), is demonstrated to catalyze epoxidation and hydroxylation with H2O2 as an oxidant.
Keywords :
epoxidation , dicopper complexes , X-ray crystal structures , disulfides
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
