Title of article :
Palladium-catalyzed stereoselective C-glycosidation of unprotected enones derived from d-glucal with trimethylsilyl cyanide
Author/Authors :
Hayashi، نويسنده , , Masahiko and Kawabata، نويسنده , , Hirotoshi and Shimono، نويسنده , , Satoshi and Kakehi، نويسنده , , Akikazu، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
Acetylated and unprotected enones derived from d-glucal reacted with trimethylsilyl cyanide in the presence of a catalytic amount of a palladium compound in 1,4-addition fashion to afford the corresponding 3-keto-glycosyl cyanides in high yield and in high α-selectivity.
Keywords :
palladium and compounds , enones , C-glycosidation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
