Author/Authors :
Venerando Pistarà، نويسنده , , Venerando and Barili، نويسنده , , Pier Luigi and Catelani، نويسنده , , Giorgio and Corsaro *، نويسنده , , Antonino and D’Andrea، نويسنده , , Felicia and Fisichella، نويسنده , , Salvatore، نويسنده ,
Abstract :
The inosose derivative 3 was obtained with high stereoselectivity by intramolecular aldol condensation of the aldohexos-5-ulose derivative 2, and it was selectively reduced and debenzylated to give epi-inositol in high yield. The stereochemistry and the preferred conformations of compounds 3–7 were determined through 1D and 2D NMR experiments.
Keywords :
intramolecular aldol condensations , Inositols , carbohydrates , Reduction
