Title of article
A versatile synthesis of 9-BBN derivatives from organometallic reagents and 9-(triisopropylsilyl)thio-9-borabicyclo[3.3.1]nonane
Author/Authors
Soderquist، نويسنده , , John A and Justo de Pomar، نويسنده , , Jorge C، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
3
From page
3537
To page
3539
Abstract
Representative B-substituted-9-BBNs (3) are efficiently prepared from either organolithium or Grignard reagents through their addition to (TIPS)S-9-BBN (1) which is readily available from TIPSSH and 9-BBN-H. The thermally induced collapse of the intermediate ‘ate’ complexes (2) produces 3 which is easily isolated in good yield and high purity.
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637478
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