Title of article
Studies in the aza-Cope reaction: a formal highly enantioselective synthesis of tryprostatin B
Author/Authors
Carla Sofia Cardoso، نويسنده , , A and Lobo، نويسنده , , Ana M and Prabhakar *، نويسنده , , Sundaresan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
3
From page
3611
To page
3613
Abstract
The BF3–Et2O induced rearrangement of N-phthaloyl-1-(3,3-dimethylallyl)-l-tryptophane methyl ester proceeds without significant loss of its optical integrity to provide its 2-(3,3-dimethylallyl) isomer, a key intermediate in the synthesis of tryprostatin B.
Keywords
sigmatropic rearrangements , Enantioselection , natural product , indoles
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637527
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